Nonsulfide zinc deposits in the Silesia–Cracow district,Southern Poland     

Vito Coppola  Maria Boni  H. Albert Gilg  Bozena Strzelska-Smakowska 《Mineralium Deposita》2009,44(5):559-580

The Silesia–Cracow district in Poland has been one of the world’s principal sources of zinc from nonsulfide zinc ore (Polish: galman). The still remaining nonsulfide ore resources can be estimated at 57 Mt at 5.6% Zn and 1.4% Pb. Nonsulfide mineralization is mainly hosted by Lower Muschelkalk (Triassic) limestone and is associated with different generations of the hydrothermal ore-bearing dolomite (OBD I, II, III). A fundamental ore control is believed to have been exerted by the basement faults, which were repeatedly reactivated during the Alpine tectonic cycle, leading to the formation of horst-and-graben structures: these dislocations may have caused short periods of emersion and the circulation of meteoric waters during the Cenozoic. Nonsulfide ores show a wide range of morphological characteristics and textures. They occur as earthy masses, crystalline aggregates, and concretions in cavities. Breccia and replacement textures are also very common. The most important mineral phases are: smithsonite, Fe–smithsonite, Zn–dolomite, goethite, and Fe–Mn(hydr)oxides. Minor hemimorphite and hydrozincite have also been detected. Two distinct nonsulfide ore types occur: the predominant red galman and the rare white galman. In the white galman, Fe–smithsonite and Zn–dolomite are particularly abundant. This ore type is commonly considered as a peripheral hydrothermal alteration product related to the same fluids that precipitated both the OBD II–III and the sulfides. In contrast, a supergene origin is commonly assumed for the red galman. Evidence of the petrographic and mineralogical difference between white and red galman is also found in stable isotope data. Smithsonite from red galman shows a limited range of δ ¹³C_VPDB values (−10.1 to −11.4‰), and δ ¹⁸O_VSMOW values (25.3‰ to 28.5‰, mean 26.8 ± 0.3‰). The uniform and low carbon isotope values of red galman smithsonite are unusual for supergene carbonate-hosted deposits and indicate the predominance of a single organic carbon source. Smithsonite from white galman has a more variable, slightly more positive carbon isotope (−2.9‰ to −7.4‰), but broadly similar oxygen isotope composition (26.8‰ to 28.9‰). The relationship of the white galman ore with the hydrothermal system responsible for OBD II and sulfide generation is still uncertain. The most important paleoweathering events took place in both Lower and Upper Silesia during Late Cretaceous up to Paleogene and early Neogene time. During this period, several short-lasting emersions and intense weathering episodes facilitated the formation of sinkholes in the Triassic carbonate rocks and the oxidation of sulfide orebodies through percolating meteoric waters. These phenomena may have lasted until the Middle Miocene.  相似文献   

Quantitative reconstruction of Holocene precipitation changes in southern Patagonia     

Marcela Sandra Tonello  Maria Virginia Mancini  Heikki Sepp 《Quaternary Research》2009,72(3):410-420

Holocene variations in annual precipitation (P_ann) were reconstructed from pollen data from southern Argentinian Patagonia using a transfer function developed based on a weighted-averaging partial least squares (WA-PLS) regression. The pollen–climate calibration model consisted of 112 surface soil samples and 59 pollen types from the main vegetation units, and modern precipitation values obtained from a global climate database. The performance (r² = 0.517; RMSEP = 126 mm) of the model was comparable or slightly lower than in other comparable pollen–climate models. Fossil pollen data were obtained from a sediment core from Cerro Frias site (50°24'S, 72°42'W) located at the forest-steppe ecotone. Reconstructed P_ann values of about 200 mm suggest dry conditions during the Pleistocene–Holocene transition (12,500–10,500 cal yr BP). P_ann values were about 300–350 mm from 10,500 to 8000 cal yr BP and increased to 400–500 mm between 8000 and 1000 cal yr BP. An abrupt decrease in P_ann at about 1000 cal yr BP was associated with a Nothofagus decline. The reconstructed P_ann suggests a weakening and southward shift of the westerlies during the early Holocene and intensification, with no major latitudinal shifts, during the mid-Holocene at high latitudes in southern Patagonia.  相似文献   

Influence of high-pressure processing on the structure and memory effect of synthetic layered double hydroxides     

Jaqueline C. Rodrigues  Tania Maria Haas Costa  Márcia R. Gallas  Celso C. Moro 《Physics and Chemistry of Minerals》2009,36(8):439-446

We investigate the structural evolution of synthetic layered double hydroxides (LDH) samples, processed at room temperature and high-pressure (up to 7.7 GPa) in a toroidal chamber with two pressure-transmitting media, lead and graphite, using X-ray diffraction, thermogravimetry and N₂-adsorption isotherms techniques. The X-ray patterns of compacted samples show a decrease in the peak intensities. For both pressure-transmitting media, our samples revealed a reduction of the basal d-spacing for the (003) plane when processed at 7.7 GPa. The expected high-pressure-induced amorphization was not observed. Surprisingly, we find high-pressure processing to have a strong influence on the memory effect of the LDH, due essentially to the reduction of the surface area and pore closing. Even when immersed in water, our samples did not recover the LDH structure, when either calcined at 450°C and compacted at 7.7 GPa, or calcined at 700°C and immediately compacted at 2.5 and 7.7 GPa.  相似文献   

Youth empowerment and information and communication technologies: a case study of a remote Australian Aboriginal community     

Guy Singleton  Maria Fay Rola-Rubzen  Kado Muir  Deeva Muir  Murray McGregor 《GeoJournal》2009,74(5):403-413

In spite of a ‘digital divide’, Aboriginal groups in Australia, as internationally, are increasingly using information and communication technologies (ICTs) to maintain their cultures, communicate, archive knowledge, empower their communities, develop skills and generate income. Each community uses the technologies differently in accordance with their particular needs and the opportunities available. The use of ICTs in Aboriginal youth empowerment is illustrated through a case study of an initiative undertaken by the Walkatjurra Cultural Centre in Leonora, remote Western Australia. A participatory process was used to engage the Centre’s young people and they were given individual assistance to develop their ICT related capacity. The community conceives this youth empowerment to be part of a broader youth participation process that will contribute to the Centre’s overall objectives.  相似文献   

Empty marine container logistics: facts,issues and management strategies     

Sotirios Theofanis  Maria Boile 《GeoJournal》2009,74(1):51-65

With the global container population exceeding 25 million TEU (Twenty-foot Equivalent Unit) and the annual production of new boxes exceeding 3 million TEU it is estimated that around 1.5 million TEU of empty containers are sitting in yards and depots around the world waiting for use. Although utilization rates have improved since 2004, container utilization depends on the very dynamic nature of container transportation, and the container building and leasing industries. Owing primarily to the chronic trend of increasing trade imbalances across the oceans, and despite recent trends along some trade routes, the empty container management problem has become a major issue for the container shipping industry during the last decade. This paper examines and analyzes empty container logistics at a global, interregional, regional and local level. Special consideration is given to key factors affecting the empty container logistics management and strategies implemented by ocean carriers and other stakeholders to better manage empty containers.

Maria BoileEmail:

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Predictions of Energy and Helicity in Four Major Eruptive Solar Flares   总被引：1，自引：0，他引：1  

Maria D. Kazachenko  Richard C. Canfield  Dana W. Longcope  Jiong Qiu 《Solar physics》2012,277(1):165-183

In order to better understand the solar genesis of interplanetary magnetic clouds (MCs), we model the magnetic and topological properties of four large eruptive solar flares and relate them to observations. We use the three-dimensional Minimum Current Corona model (Longcope, 1996, Solar Phys. 169, 91) and observations of pre-flare photospheric magnetic field and flare ribbons to derive values of reconnected magnetic flux, flare energy, flux rope helicity, and orientation of the flux-rope poloidal field. We compare model predictions of those quantities to flare and MC observations, and within the estimated uncertainties of the methods used find the following: The predicted model reconnection fluxes are equal to or lower than the reconnection fluxes inferred from the observed ribbon motions. Both observed and model reconnection fluxes match the MC poloidal fluxes. The predicted flux-rope helicities match the MC helicities. The predicted free energies lie between the observed energies and the estimated total flare luminosities. The direction of the leading edge of the MC’s poloidal field is aligned with the poloidal field of the flux rope in the AR rather than the global dipole field. These findings compel us to believe that magnetic clouds associated with these four solar flares are formed by low-corona magnetic reconnection during the eruption, rather than eruption of pre-existing structures in the corona or formation in the upper corona with participation of the global magnetic field. We also note that since all four flares occurred in active regions without significant pre-flare flux emergence and cancelation, the energy and helicity that we find are stored by shearing and rotating motions, which are sufficient to account for the observed radiative flare energy and MC helicity.  相似文献   

N-body integrators with individual time steps from Hierarchical splitting     

Federico I. Pelupessy  Jürgen Jänes  Simon Portegies Zwart 《New Astronomy》2012,17(8):711-719

We review the implementation of individual particle time-stepping for N-body dynamics. We present a class of integrators derived from second order Hamiltonian splitting. In contrast to the usual implementation of individual time-stepping, these integrators are momentum conserving and show excellent energy conservation in conjunction with a symmetrized time step criterion. We use an explicit but approximate formula for the time symmetrization that is compatible with the use of individual time steps. No iterative scheme is necessary. We implement these ideas in the HUAYNO¹ code and present tests of the integrators and show that the presented integration schemes shows good energy conservation, with little or no systematic drift, while conserving momentum and angular momentum to machine precision for long term integrations.  相似文献   

First ever in situ observations of Venus’ polar upper atmosphere density using the tracking data of the Venus Express Atmospheric Drag Experiment (VExADE)     

P. Rosenblatt  S.L. Bruinsma  I.C.F. Müller-Wodarg  B. Häusler  H. Svedhem  J.C. Marty 《Icarus》2012,217(2):831-838

On its highly elliptical 24 h orbit around Venus, the Venus Express (VEX) spacecraft briefly reaches a periapsis altitude of nominally 250 km. Recently, however, dedicated and intense radio tracking campaigns have taken place in August 2008, October 2009, February and April 2010, for which the periapsis altitude was lowered to the 186–176 km altitude range in order to be able to probe the upper atmosphere of Venus above the North Pole for the first time ever in situ. As the spacecraft experiences atmospheric drag, its trajectory is measurably perturbed during the periapsis pass, allowing us to infer total atmospheric mass density at the periapsis altitude. A Precise Orbit Determination (POD) of the VEX motion is performed through an iterative least-squares fitting process to the Doppler tracking data, acquired by the VEX radioscience experiment (VeRa). The drag acceleration is modelled using an initial atmospheric density model (VTS3 model, Hedin, A.E., Niemann, H.B., Kasprzak, W.T., Seiff, A. [1983]. J. Geophys. Res. 88, 73–83). A scale factor of the drag acceleration is estimated for each periapsis pass, which scales Hedin’s density model in order to best fit the radio tracking data. Reliable density scale factors have been obtained for 10 passes mainly from the second (October 2009) and third (April 2010) VExADE campaigns, which indicate a lower density by a factor of about 1.8 than Hedin’s model predicts. These first ever in situ polar density measurements at solar minimum have allowed us to construct a diffusive equilibrium density model for Venus’ thermosphere, constrained in the lower thermosphere primarily by SPICAV-SOIR measurements and above 175 km by the VExADE drag measurements (Müller-Wodarg et al., in preparation). The preliminary results of the VExADE campaigns show that it is possible to obtain with the POD technique reliable estimates of Venus’ upper atmosphere densities at an altitude of around 175 km. Future VExADE campaigns will benefit from the planned further lowering of VEX pericenter altitude to below 170 km.  相似文献   

Analysis of energetic electron drop-outs in the upper atmosphere of Titan during flybys in the dayside magnetosphere of Saturn     

Z. Bebesi  N. Krupp  K. Szego  M. Fränz  Z. Nemeth  S.M. Krimigis  D.G. Mitchell  G. Erdos  D.T. Young  M.K. Dougherty 《Icarus》2012,218(2):1020-1027

We discuss the high energy electron absorption signatures at Titan during the Cassini dayside magnetospheric encounters. We use the electron measurements of the Low Energy Measurement System of the Magnetospheric Imaging Instrument. We also examine the mass loading boundary based on the ion data of the Ion Mass Spectrometer sensor of the Cassini Plasma Spectrometer. The dynamic motion of the Kronian magnetopause and the periodic charged particle flux and magnetic field variations – associated with the magnetodisk of Saturn – of the subcorotating magnetospheric plasma creates a unique and complex environment at Titan. Most of the analysed flybys (like T25–T33 and T35–T51) cluster at similar Saturn Local Time positions. However the instantaneous direction of the incoming magnetospheric particles may change significantly from flyby to flyby due to the very different magnetospheric field conditions which are found upstream of Titan within the sets of encounters.The energetic magnetospheric electrons gyrate along the magnetic field lines of Saturn, and at the same time bounce between the mirror points of the magnetosphere. This motion is combined with the drift of the magnetic field lines. When these flux tubes interact with the upper atmosphere of Titan, their content is depleted over approximately an electron bounce period. These depletion signatures are observed as sudden drop-outs of the electron fluxes. We examined the altitude distribution of these drop-outs and concluded that these mostly detected in the exo-ionosphere of Titan and sometimes within the ionosphere.However there is a relatively significant scatter in the orbit to orbit data, which can be attributed to the which can be attributed to the variability of the plasma environment and as a consequence, the induced magnetosphere of Titan. A weak trend between the incoming electron fluxes and the measured drop-out altitudes has also been observed.  相似文献   

A potentially new type of nonchondritic interplanetary dust particle with hematite,organic carbon,amorphous Na,Ca‐aluminosilicate,and FeO‐spheres     

Guillermo M. MUÑOZ CARO  Frans J. M. RIETMEIJER  Virginia SOUZA‐EGIPSY  Maria Pilar VALLES‐GONZÁLEZ 《Meteoritics & planetary science》2012,47(2):248-261

Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe₂O₃) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.  相似文献